Determination of assay for Cetyl trimethyl ammonium bromide

Aug 22, 2023

Here below is the method of analysis for Cetyl trimethyl ammonium bromide shared by Ahsuperchem:

1. Reagents and Solutions:

  1. Anhydrous Ethanol: Analytically pure
  2. Calcium Carbonate: Analytically pure
  3. Fluorescent Yellow Ethanol solution: 1g/L
  4. Silver Nitrate standard solution: c(AgNO3) = 0.1mol/L

2. Analysis Steps:

 

2.1 Weigh 0.35g (accurate to 0.0002g) sample into 50mL Ethanol, add 25mL pure water, 0.1g Calcium Carbonate and 8 drops Fluorescent Yellow Ethanol solution. Titrate by 0.1mol/L AgNO3 standard solution. The solution turn to pink red, as the titration end point.

 

2.2 Result Calculation:

Calculate the Assay X% of  Cetyl trimethyl ammonium bromide in sample according to following formula:

 

X

   V×c×364.46

m×10

 

 In formula:

         V: The consumed volume of Silver Nitrate standard solution in titration, mL

         c: Molar concentration of Silver Nitrate standard solution, mol/L

         m: Mass of measured sample, g

        364.46 - molar mass of CTAB

 

2.3 Allowable Difference

The difference between the two parallel determination results should not exceed 0.5%, taking the arithmetic mean as the determination result.

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